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Esther Takeuchi

Esther S. Takeuchi, PhD, Distinguished Professor and the William and Jane Knapp Chair at Stony Brook University is being honored by the National Academy of Sciences (NAS) and will receive the Award in Chemical Sciences. This award is in recognition of her breakthrough contributions in the understanding of electrochemical energy storage.  

Takeuchi, who holds a joint appointment at Department of Energy’s (DOE) Brookhaven National Laboratory, is an internationally recognized inventor, researcher, and educator in the fields of materials science, chemistry and renewable energy. She will be honored in a ceremony during the NAS 159th annual meeting on May 1 and will receive a medal and prize of $15,000 sponsored by the Merck Company Foundation.

The award cites Takeuchi’s contributions “to the materials and mechanistic understanding relevant to electrochemical energy storage, using chemical insight to address issues of critical importance.”

“I am sincerely honored to receive the National Academy of Science Award for Chemical Sciences,” said Takeuchi, also the Knapp Chair Professor of Energy and the Environment in the Department of Materials Science and Chemical Engineering “The fundamental chemistry of electrochemical energy storage is complex and the subsequent development of viable energy storage devices is made even more challenging by the unique demands of each application.”

Takeuchi’s research has been instrumental in energy storage improvements that meet societal needs and can be applied to electric vehicles, medical devices, and batteries that back up the power grid. Among her numerous and notable inventions is a compact lithium/silver vanadium oxide battery that increased the lifespan of implantable cardiac defibrillators, a solution that reduced the number of surgeries patients needed to undergo to replace the devices that detect and correct irregular, potentially fatal, heart rhythms.

Takeuchi was recently elected a member of the American Academy of Arts and Sciences. She has also been inducted into the National Academy of Engineering and selected as a Fellow of the American Institute for Medical and Biological Engineering and the American Association for the Advancement of Science. She was selected as the 2013 recipient of the E.V. Murphree Award in Industrial and Engineering Chemistry from the American Chemical Society. She was inducted into the National Inventors Hall of Fame in 2011. In 2009, President Obama presented Takeuchi with the National Medal of Technology and Innovation, the highest honor possible for technological achievement in the United States.

By Daniel Dunaief

Replacing batteries in a flashlight or an alarm clock requires simple effort and generally doesn’t carry any risk for the device. The same, however, can’t be said for battery-operated systems that go in human bodies and save lives, such as the implantable cardiac defibrillator, or ICD.

Earlier versions of these life-saving devices that restore a normal heart rhythm were large and clunky and required a change of battery every 12 to 18 months, which meant additional surgeries to get to the device.

Esther Takeuchi with Michaëlle Jean, the secretary general of the Organisation Internationale de la Francophonie, and moderator Fernando Tiberini at the award ceremony in Paris on June 7. Photo courtesy of European Patent Office

That’s where Esther Takeuchi, who is now Stony Brook University’s William and Jane Knapp Endowed Chair in Energy and the Environment and the chief scientist of the Energy Sciences Directorate at Brookhaven National Laboratory, has made her mark. In the 1980s, working at a company called Greatbatch, Takeuchi designed a battery that was much smaller and that lasted as long as five years. The battery she designed was a million times higher power than a pacemaker battery.

For her breakthrough work on this battery, Takeuchi has received numerous awards. Recently, the European Patent Office honored her with the 2018 innovation prize at a ceremony in Paris. Numerous high-level scientists and public officials attended the award presentation, including former French Minister of the Economy Thierry Breton, who is currently the CEO of Atos, and the Secretary General of the International Organisation of Francophony Michaëlle Jean. 

Takeuchi was the only American to win this innovation award this year.

Takeuchi’s work is “the epitome of innovation, as demonstrated in this breakthrough translational research for which she was recognized,” Dr. Samuel L. Stanley Jr., the president of Stony Brook and board chair of Brookhaven Science Associates, which manages Brookhaven National Laboratory. “Her star keeps getting brighter, and I’m proud that she is part of the Stony Brook University family.”

As a winner of this award, Takeuchi joins the ranks of other celebrated scientists, including Shuji Nakamura, who won the European Inventor Award in 2007 and went on to win the Nobel Prize in physics, and Stefan Hell from Germany, whose European Inventor Award predated a Nobel Prize in chemistry. 

Among the over 170 innovators who have won the award, some have worked on gluten substitutes from corn, some have developed drugs against multi-drug-resistant tuberculosis, and some have developed soft close furniture hinges.

“The previous recipients have had substantial impact on the world and how we live,” Takeuchi explained in an email. “It is incredible to be considered among that group.” Nominated for the award by a patent examiner from the European Patent Office, she described the award as an “honor” for the global recognition.

The inventor award is a symbolic prize in which the recipients receive attention for their work, explained Rainer Osterwalder, the director of media relations at the European Patent Office.

Takeuchi was one of four women to receive the award this year — the largest such class of women innovators.

“It was very meaningful to see so many accomplished women be recognized for their contributions,” she explained. “I was delighted to meet them and make some additional contacts with female innovators as well.”

About half the researchers in her lab, which currently includes three postdoctoral researchers and usually has about 12 to 16 graduate students, are women. Takeuchi has said that she likes being a role model for women and that she hopes they can see how it is possible to succeed as a scientist.

Implantable cardiac defibrillators are so common in the United States that an estimated 10,000 people receive them each month.

Indeed, while she was at the reception for an awards ceremony attended by over 600 people, Takeuchi said she met someone who had an ICD.

“It is very rewarding to know that they are alive due to technology and my contributions to the technology,” she explained.

Takeuchi said that many people contributed to the battery project for the ICD over the years who were employed at Greatbach. These collaborators were involved in engineering, manufacturing, quality and customer interactions, with each aspect contributing to the final product.

The battery innovation stacks alternating layers of anodes and cathodes and uses lithium silver vanadium oxide. The silver is used for high current, while the vanadium provides long life and high voltage.

Takeuchi, who earned her bachelor’s degree from the University of Pennsylvania and her doctorate from Ohio State University, has received over 150 patents. The daughter of Latvian emigrants, she received the presidential level National Medal of Technology and Innovation from Barack Obama and has been inducted into the National Inventors Hall of Fame.

Takeuchi continues to push the envelope in her energy research. “We are now involved in thinking about larger scale batteries for cars and ultimately for the grid,” she wrote in an email. “Further, we have demonstrated methods that allow battery components to be regenerated to extend their use. This could potentially minimize batteries going into land fills in the future.”

Takeuchi is one of a growing field of scientists who are using the high-tech capabilities of the National Synchrotron Light Source II at BNL, which allows her to see inside batteries as they are working.

“We recently published a paper where we were able to detect the onset of parasitic reactions,” she suggested, which is “an important question for battery lifetime.”

In the big picture, the scientist said she is balancing between power and energy content in her battery research.

“Usually, when cells need to deliver high power, the energy content goes down,” she said. “The goal is to have high energy and high power simultaneously.”

Esther Takeuchi with photo in the background of her with President Obama, when she won the 2009 National Medal of Technology and Innovation. Photo courtesy of Brookhaven National Laboratory

By Daniel Dunaief

Pop them in the back of a cell phone and they work, most of the time. Sometimes, they only do their job a short time, discharge or generate so much heat that they become a hazard, much to the disappointment of the manufacturers and the consumers who bought electronic device.

Esther Takeuchi, a SUNY distinguished professor in the Departments of Chemistry and Materials Science and Engineering and the chief scientist in the Energy Sciences Directorate at Brookhaven National Laboratory leads a team of scientists who are exploring what makes one battery work while another falters or fails. She is investigating how to improve the efficiency of batteries so they can deliver more energy as electricity.

Esther Takeuchi with a device that allows her to test batteries under various conditions to see how they function. Photo courtesy of Brookhaven National Laboratory

The process of manufacturing batteries and storing energy is driven largely by commercial efforts in which companies put the ingredients together in ways that have, up until now, worked to produce energy. Scientists like Takeuchi, however, want to know what’s under the battery casing, as ions and electrons move beneath the surface to create a charge.

Recently, Takeuchi and a team that includes her husband Kenneth Takeuchi and Amy Marschilok, along with 18 postdoctoral and graduate students, made some progress in tackling energy storage activity in iron oxides.

These compounds have a mixed track record among energy scientists. That, Takeuchi said, is what attracted her and the team to them. Studying the literature on iron oxides, her graduate students discovered “everything from, ‘it looks terrible’ to, ‘it looks incredibly good,’” she said. “It is a challenging system to study, but is important to understand.”

This offered promise, not only in finding out what might make one set of iron oxides more effective in holding a charge without generating heat — the energy-robbing by-product of these reactions — but also in providing a greater awareness of the variables that can affect a battery’s performance.

In addition to determining how iron oxides function, Takeuchi would like to “determine whether these [iron oxides] can be useful and workable.” Scientists working with iron oxides didn’t know what factors to control in manufacturing their prospective batteries.

Takeuchi said her group is focusing on the linkage between small-scale and mesoscale particles and how that influences battery performance. “The benefit of iron oxides is that they are fairly inexpensive, are available, and are nontoxic,” she said, and they offer the potential of high energy content. They are related to rust in a broad sense. They could, theoretically, contain 2.5 times more energy than today’s batteries. “By understanding the fundamental mechanisms, we can move forward to understand their limitations,” she said, which, ultimately, could result in making these a viable energy storage material. T

akeuchi is also looking at a manganese oxide material in which the metal center and the oxygen connect, creating a tube-like structure, which allows ions to move along a track. When she started working with this material, she imagined that any ion that got stuck would cause reactions to stop, much as a stalled car in the Lincoln Tunnel leads to long traffic delays because the cars behind the blockage have nowhere to go.

Takeuchi said the ions don’t have the same problems as cars in a tunnel. She and her team believe the tunnel walls are porous, which would explain why something that looks like it should only produce a result that’s 5 percent different instead involves a process that’s 80 percent different. “These escape points are an interesting discovery, which means the materials have characteristics that weren’t anticipated,” Takeuchi said. The next step, she said, is to see if the researchers can control the technique to tune the material and make it into the constructs that take advantage of this more efficient flow of ions.

Through a career that included stops in Buffalo and North Carolina and West Virginia, Takeuchi, who has over 150 patents to her name, has collected numerous awards and received considerable recognition. She won the 2009 National Medal of Technology and Innovation, a presidential award given at a ceremony in the West Wing of the White House. Takeuchi developed compact lithium batteries for implantable cardiac defibrillators.

Takeuchi is currently a member of the National Medal of Technology and Innovation Nomination Evaluation Committee, which makes recommendations for the medal to the president. Scientists who have known Takeuchi for years applaud the work she and her team are doing on Long Island. “Dr. Takeuchi and her research group are making great advances in battery research that are very clearly promoted by the strong relationship between Stony Brook and BNL,” said Steven Suib, the director of the Institute for Materials Science at the University of Connecticut.

Indeed, at BNL, Takeuchi has used the National Synchrotron Light Source II, which became operational last year. The light source uses extremely powerful X-rays to create incredibly detailed images. She has worked with three beamlines on her research. At the same time, Takeuchi collaborates with researchers at the Center for Functional Nanomaterials at BNL.

Although she works with real-world experiments, Takeuchi partners with scientists at Stony Brook, BNL and Columbia University who focus on theoretical possibilities, offering her an insight into what might be happening or be possible. There are times when she and her team have observed some interaction with batteries, and she’s asked the theorists to help rationalize her finding. Other times, theorists have suggested what experimentalists should search for in the lab.

A resident of South Setauket, Takeuchi and her husband enjoy Long Island beaches. Even during the colder weather, they bundle up and enjoy the coastline. “There’s nothing more mentally soothing and energizing” than going for a long walk on the beach, she said.

In her research, Takeuchi and her team are focused on understanding the limitations of battery materials. Other battery experts believe her efforts are paying dividends. Suib said the recent work could be “very important in the development of new, inexpensive battery materials.”

JoAnne Hewett. Twitter photo

By Daniel Dunaief

Daniel Dunaief

Finally!

Brookhaven National Laboratory has had nine lab directors since it was founded in 1946. Earlier this week, the Department of Energy facility, which has produced seven Nobel Prizes, has state-of-the-art facilities, and employs over 2,800 scientists and technicians from around the world announced that it hired JoAnne Hewett as its first female lab director.

Successful, determined, dedicated and award-winning local female scientists lauded the hire of Hewett, who comes to BNL from SLAC National Accelerator Laboratory where she was associate lab director for fundamental physics and chief research officer. SLAC is operated by Stanford University in Menlo Park, California. In email responses, local female scientists suggested that Hewett’s hiring can and would inspire women in science, technology, engineering and math (STEM) fields.

“I am so delighted by the news that Dr. JoAnne Hewett has been named to be the next director of Brookhaven National Laboratory,” wrote Esther Takeuchi, William and Jane Knapp chair in Energy and the Environment and SUNY distinguished professor at Stony Brook University and chair of the Interdisciplinary Science Department at BNL. As the first female director for the lab, Hewett “is an inspiration not only for the women who are in the field, but for future female scientists who will witness first hand that success at the highest level.”

Stella Tsirka, SUNY distinguished professor in the Department of Pharmacological Sciences at the Renaissance School of Medicine at Stony Brook University, suggested this hire was a part of an increasing number of women in prominent positions in science at local institutions.

Stony Brook and BNL are “becoming a hub of strong female role models for younger females, in STEM, in medicine, in leadership!” Tsirka wrote. “Between [SB President] Maurie McInnis, Hewett, Ivet Bahar (the director of the Laufer Center), Anissa Abi-Dargham [principal investigator for the Long Island Network for Clinical and Translational Science] and many other successful female faculty in leadership positions, hopefully, the message comes out loud and clear to our young women who are in science already, or aspire to be in science.”

For her part, Abi-Dargham, who is chair in the Department of Psychiatry and Behavioral Health, described Hewett’s hire as “amazing” and suggested it was “really exciting to see an accomplished female scientist selected to head our collaborating institution at BNL!”

Cold Spring Harbor Laboratory Professor and Cancer Center Program co-leader Mikala Egeblad added that the significance of Hewett’s hire goes “well beyond inspiring young girls. It is important to have women leaders for all sciences, also for someone at my career stage. I hope that one day, we will get to a point when we don’t think about whether a leader is a woman or a man.”

Women remain underrepresented at top leadership positions, so Egeblad finds it “very inspiring to see a woman recognized for her leadership skills and selected” to head BNL.

Leemor Joshua-Tor, professor and HHMI investigator at CSHL, called the hire “really great news” and indicated this was “especially true for the physical sciences, where there are even fewer women in senior positions than in biology.” Joshua-Tor added that the more women in senior, visible positions, “the more young women and girls see this as a normal career to have.”

Alea Mills, professor and Cancer Center member at CSHL, wrote that it is “fantastic that BNL has found the very best scientist to lead them into their next new mission of success. And it’s an extra bonus that this top scientist happens to be a woman!”

Mills added that efforts to enhance diversity are fashionable currently, but all too often fall short. Hiring Hewett makes “real traction that will undoubtedly inspire future generations of young women in STEM.”

Patricia Wright, distinguished service professor at Stony Brook in the Department of Anthropology, wrote that it was “inspiring” to see a female director of BNL and that “young female scientists can aspire to being in that role some day.”

Peng Zhang, center, with four of his students from his power systems class, from left, Marissa Simonelli, Ethan Freund, Kelly Higinbotham and Zachary Sola, who were selected as IEEE Power and Engergy Scholars in 2017. Photo by Mary McCarthy

By Daniel Dunaief

If Peng Zhang succeeds in his work, customers on Long Island and elsewhere will no longer lose power for days or even hours after violent storms.

One of the newest additions to the Department of Electrical and Computer Engineering at Stony Brook University, Zhang, who is the SUNY Empire Innovation associate professor, is enhancing the resiliency and reliability of microgrids that may be adaptable enough to provide energy to heat and light a home despite natural or man-made disruptions. Unlike the typical distributed energy network of most utilities around the country, microgrids are localized and can function on their own.

Peng Zhang. Photo from SBU

A microgrid is a “central theme of our research,” said Zhang, who joined Stony Brook at the beginning of September. “Even when a utility grid is down because of a hurricane or an attack, a microgrid is still able to supply the local customers” with power. He is also using quantum information science and quantum engineering to empower a resilient power grid.

Zhang expects that the microgrid and utility grid will be more resilient, stable and reliable than the current system. A microgrid will provide reliable power even when a main grid is offline. The microgrid wouldn’t replace the function of the grid in the near future, but would enhance the electricity resilience for customers when the central utility is unavailable or unstable.

Part of his motivation in working in this field comes from his own experience with a weather-related loss of power. 

Even though Zhang, who used his training in mathematics to develop an expertise in power systems, had been working on wind farms and their grid integration, he decided after Hurricane Irene and a nor’easter that he should do more research on how to restore power after a utility became unavailable.

Irene hit in August, while the nor’easter knocked out power in the winter. After the storms, Northeast Utilities, which is currently called Eversource Energy, asked him to lead a project to recommend solutions to weather-induced outages.

Zhang plans to publish a book through Cambridge University Press this year called “Networked Microgrids,” which not only includes his previous results but also presents his vision for the future, including microgrids that are self-healing, self-protected, self-reconfiguring and autonomous.

He recognizes that microgrids, which are becoming increasingly popular in the energy community, present a number of challenges for customers. For starters, the cost, at this point, for consumers can be prohibitively high.

Zhang can cut those expenses, however, by replacing hardware upgrades with software, enabling more of the current system to function with greater resilience without requiring as many costly hardware modifications.

His National Science Foundation project on programmable microgrids will last until next year. He believes he will be able to verify most of the prototypes for the programmable microgrid functions by then.

Zhang called advances in energy storage a “key component” that could improve the way microgrids control and distribute power. Energy storage can help stabilize and improve the resilience of microgrids.

He is eager to work with Esther Takeuchi, who has dual appointments at Stony Brook University and Brookhaven National Laboratory, not only on microgrid technologies but also on renewable integration in the transmission grid.

Zhang appreciates SBU’s reputation in physics, applied math, computer science and electrical and computer engineering. When he was young, he said he also heard about and saw Chen-Ning Yang, whom he described as a model and legend.

“I feel proud and honored to be working at Stony Brook where Dr. Yang taught for more than three decades,” he stated in an email.

In his lab, Zhang has six doctoral students, one visiting doctoral student and two master’s students. A postdoctoral researcher, Yifan Zhou, who worked with him at the University of Connecticut, will soon join his Long Island lab.

Zhang, who earned doctorates from Tsinghua University and the University of British Columbia, brought along a few grants from the University of Connecticut where he held two distinguished titles.

Zhang has “high expectations for the people who work for him,” Peter Luh, a board of trustees distinguished professor at the University of Connecticut, explained in an email. “However, he is considerate and helps them achieve their goals.”

Zhou, who comes from Tsinghua University, is working with him on stability issues in microgrids to guarantee their performance under any possible scenario, from a major storm to a cyberattack.

Zhang is working with Scott Smolka and Scott Stoller, both in the Computer Science Department  at Stony Brook, on resilient microgrids

“We are planning to use simulations and more rigorous methods for formal mathematical analysis of cyberphysical systems to verify resiliency properties in the presence of fault or attacks,” said Stoller who described Zhang as a “distinguished expert on electric power systems and especially microgrids. His move to Stony Brook brings significant new expertise to the university.”

The Stony Brook scientists have created an exercise in which they attack his software systems, while he tries to ensure its ongoing reliability. Zhang will develop defense strategies to guarantee the resilience and safety of the microgrids.

Zhang was born in Shandong Province in China. He is married to Helen Wang, who works for a nonprofit corporation as an electrical engineer. The power couple has three sons: William, 13, Henry 10, and Benjamin, 8. They are hoping their sons benefit from the public school system on Long Island.

Zhang’s five-year goal for his work involves building an institute for power engineering, which will focus on microgrids and other future technologies. This institute could have 20 to 30 doctoral students.

An ambitious researcher, Zhang would like to be the leader in microgrid research in the country. “My goal is to make Stony Brook the top player in microgrid research in the U.S.,” he said.

Meng Yue, scientist in the Sustainable Energy Technologies Department at Brookhaven National Laboratory who has been collaborating with Zhang for over five years, anticipates that Zhang’s research will help consumers.

“As New York State has more aggressive renewable portfolio, I believe the research achievements will soon advance technologies in the power grid application,” he said.

 

Standing near one of the X-ray scattering instruments, Kevin Yager holds a collection of samples, including a self-assembling polymer film. Photo courtesy of BNL

By Daniel Dunaief

Throw a batch of LEGOs in a closed container and shake it up. When the lid is opened, the LEGOs will likely be spread out randomly across the container, with pieces facing different directions. Chances are few, if any, of the pieces will stick together. Attaching strong magnets to those pieces could change the result, with some of the LEGOs binding together. On a much smaller scale and with pieces made from other parts, this is what researchers who study the world of self-assembled materials do.

Scientists at the Center for Functional Nanomaterials and at the National Synchrotron Light Source II at Brookhaven National Laboratory experiment with small parts that will come together in particular ways based on their energy landscapes through a process called self-assembly.

Every so often, however, a combination of steps will alter the pathway through the energy landscape, causing molecules to end up in a different final configuration. For many scientists, these so-called nonequilibrium states are a nuisance.

Above, Kevin Yager listens to sonified data. When data is sonified, it is translated into sound. Photo by Margaret Schedel

For Kevin Yager, they are an opportunity. A group leader at the CFN who works closely with the NSLS-II, the McGill University-educated Yager wants to understand how the order of these steps can change the final self-assembled product. “In the energy landscape, you have these peaks and valleys and you can take advantage of that to move into a particular state you want,” Yager said. “The high level goal is that, if we understand the fundamentals well enough, we can have a set of design rules for any structure we can dream up.”

At the CFN, Yager manages a nanofabrication facility that uses electron-beam lithography and other techniques to make nanostructures. He would like to fabricate model batteries to show the power of nanomaterials. He is also determined to understand the rules of the road in the self-assembly process, creating the equivalent of an instruction manual for miniature parts.

In future years, this awareness of nonequilibrium self-assembly may lead to revolutionary innovations, enabling the manufacture of parts for electronics, drugs to treat disease and deliver medicine to specific locations in a cell and monitors for the detection of traces of radioactivity or toxins in the environment, among many other possibilities.

Yager’s colleagues saw considerable opportunities for advancement from his work. Nonequilibrium self-assembly has “significant potential for a broad range of nanodevices and materials due to its ability to create complex structures with ease,” Oleg Gang, a group leader in Soft and Bio Nanomaterials at the CFN, explained in an email. Yager is an “excellent scientist” who produces “outstanding results.”

One of the things Yager hopes his research can develop is a way to “trick self-assembly into making structures they don’t natively want to make” by using the order of steps to control the final result.

As an example, Yager said he developed a sequence of steps in which nanoscale cylinders pack hexagonal lattices into a plane. These lattices tend to point in random directions as the cylinders form. By following several steps, including sheer aligning a plane and then thermal processing, the cylinders flip from horizontal to vertical as they inherit the alignment of the sheered surface. Flipping these cylinders, in turn, causes the hexagons all to point in the same direction. When Yager conducted these steps in a different order, he produced a different structure.

Broadly speaking, Yager is working on stacking self-assembling layers. In his case, however, the layers aren’t like turkey and swiss cheese on a sandwich, in which the order is irrelevant to the desired final product. Each layer has a hand in directing the way the subsequent layers stack themselves. Choosing the sequence in which he stacks the materials controls their structure.

Yager is working with Esther Takeuchi and Amy Marschilok at Stony Brook University to develop an understanding of the nanostructure of batteries. Gang suggested that Yager’s expertise is “invaluable for many scientists who are coming to the CFN to characterize nanomaterials using synchtrotron methods. In many cases, it would probably be impossible to achieve such quantitative understanding without [Yager’s] input.”

Yager and his wife Margaret Schedel, an associate professor in the Department of Music at Stony Brook University who is a cellist and a composer, live in East Setauket. The couple combined their talents when they sought ways to turn the data produced by the CFN, the NSLS and the NSLS-II into sound.

Scientists typically convert their information into visual images, but there’s “no reason we can’t do that with sound,” Yager said. “When you listen to data, you sometimes pick up features you wouldn’t have seen.”

One of the benefits of turning the data into sound is that researchers can work on something else and listen to the collection of data in the background, he said. If anything unexpected happens, or there is a problem with a sample or piece of equipment, they might hear it and take measures more rapidly to correct the process. “This started as a fun collaboration,” Yager said, “but it is useful.”

Schedel is working on sonifying penguin data as well. She also sonified wave data on Long Island. “By listening to the tides quickly, larger patterns emerge,” she said, adding that Yager thought the idea was theoretically interesting until he listened to misaligned data and then he recognized its benefit.

Schedel’s goal is to see this sonification effort spread from one beamline to all of them and then to the Fermilab near Chicago and elsewhere. She wants sonification to become “an ear worm in the science community.”

While Schedel introduced Yager to the world of sound in his research, he introduced her to sailing, an activity he enjoyed while growing up in the suburbs of Montreal. When she sails with him, they are “half in and half out of the boat,” Schedel said. It’s like two people “flying a kite, but you are the kite. You have to learn how to counterbalance” the boat. They hike out so they can take turns faster without tipping over, she said.

HXN team members, from left, Evgeny Nazaretski, Ken Lauer, Sebastian Kalbfleisch, Xiaojing Huang, Yong Chu, Nathalie Bouet and Hanfei Yan. Photo courtesy of BNL

By Daniel Dunaief

There’s precision in measurements and then there’s the world of Yong Chu. The head of a beamline that’s housed off to the side in a separate, concrete structure from similar efforts at Brookhaven National Laboratory, Chu led the design, construction and commissioning of a sophisticated beamline with a resolution of as low as 3 nanometers, which he hopes will get down to 1 nanometer within a year.

Just as a measure of contrast, a human hair is about 80,000 nanometers wide. Why so fine a resolution? For starters, seeing objects or processes at that high level can offer insights into how they function, how to improve their manufacture or how to counteract the effects of harmful processes.

With a battery, for example, the Hard X-ray Nanoprobe, or HXN beamline, could help reveal structural weaknesses in the nanostructure that could cause safety issues. In biology, numerous functions involve sub-cellular organelles that respond to proteins. Proteins are typically smaller than the HXN beamline can image, although researchers can tag the proteins with metals, which allows Chu, his colleagues and visiting scientists to see an aggregate of these proteins.

The HXN beamline can also help explore environmental problems, such as how plants transport harmful nanoparticles to their fruits or how artificial compounds absorb nuclear waste. Imaging beamlines that use micro-focused beams typically offer spatial resolution of 10 microns, 1 micron or even 100 nanometers, according to Ryan Tappero, the head scientist at the X-ray Fluorescence Microprobe at BNL, who has used the HXN for his research. Using the NSLS II source properties and a new x-ray optics development routinely offers resolution of 10 nanometers, which pushes the spatial resolution down by another factor of 10, which makes the HXN, according to Tappero, a “game changer.”

Tappero described Chu as a “rock star” and suggested he was an “exceptional beamline scientist” who is “very knowledgeable about X-ray optics.”

BNL houses 19 beamlines at the National Synchrotron Light Source II, a state-of-the-art facility large enough that scientists ride adult tricycles inside it to travel from one beamline to another and to transport supplies around the facility. BNL is building another nine beamlines that it hopes to have operational within the next 18 months. Each of these beamlines offers a different way to explore the world of matter. Some beamlines do not use a focused beam, while others produce beams with high angular or high energy resolution. Imaging beamlines such as the HXN produce a small beam size.

The HXN beamline has the highest spatial resolution of any beamline at the NSLS-II. Scientists building the HXN grew a nanofocusing lens with a dedicated deposition system that was constructed at the NSLS-II Research and Development lab. The system grew a nanofocusing lens a layer at a time, alternating materials and controlling the thickness at better than 1 nanometer, Chu explained.

The beamline where Chu works has padded walls, a door separating it from the rest of the light source and a monitor that records the temperature to the thousandths of a degree. “We are constantly monitoring the temperature around the X-ray microscope and inside of the X-ray microscope chamber,” he said. Around the microscope, he can keep the temperature stable within 0.03 degree Celsius. In the chamber, the scientists maintain the temperature at better than 0.003 degree Celsius.

So, now that Chu and his colleagues built their beamline, have the scientists come? Indeed, the interest in using the HXN has been well above the available time slots. For the three cycles each year, BNL receives about four requests for each available time. This reflects the unique qualities of the instrument, Chu said, adding that he doesn’t expect the rate to drop considerably, even as the HXN continues to operate, because of the ongoing demand.

Researchers have to go through a peer review process, where their ideas are graded for the likelihood of success and for the opportunity to learn from the experiments. All beam time proposals are reviewed by external expert panels, which examine the scientific merit, appropriateness of use of the facility, capability of proposers and quality of prior performance and the research plan and technical feasibility.

Chu fields about 10 calls per month from scientists who want to speak with him about the feasibility of their ideas. He may suggest another station at the NSLS-II or at the Advanced Photon Source at Argonne National Laboratory in Chicago, where he was a beamline scientist starting in 1999.

“I know many of the beamlines” at the Advanced Photon Source, he said. “I recommend some of the potential users to perform experiments at the APS first before coming to the HXN.” By the time scientists arrive at his beamline, Chu said he’s gotten to know them through numerous discussions. He considers them “as a guest” at the HXN hotel. “We try to make sure the experimental needs for the users are met as much as possible,” he said.

The HXN beamline has three staff scientists and two postdoctoral fellows who remain in contact with scientists who use the facility. “For most of the users, at least one of us is working throughout the weekends and late evenings,” said Chu.

Not just a staff scientist, Chu is also a user of the HXN, with currently one active general user proposal through a peer review process in which he is collaborating with Stony Brook University and BNL scientist Esther Takeuchi to explore the nanostructure of metal atoms during phase separation in batteries.

Chu and his wife Youngkyu Park, who works at Cold Spring Harbor Laboratory as a research investigator in basic and preclinical cancer research, live in Northport. The couple’s 22-year-old son Luke is attending Nassau Community College and is planning to transfer to Stony Brook this fall to study engineering. Their daughter Joyce is 18 and is enrolled in the Parsons School of Design in New York.

Chu grew up in Seoul, South Korea, and came to the United States when he was 18. He attended Caltech. While Chu’s parents wanted him to become a doctor, he was more inspired by a cartoon called Astro Boy, in which a scientist, Dr. Tenma, is a hero solving problems. As for the work of the scientists who visit his beamline, Chu said the “success of individual users is the success of the beamline.”

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They help start car engines, provide light in the darkness, keep music playing as joggers circumnavigate their towns, and help send signals to hearts that might otherwise have irregular beats. They are, of course, batteries.

The fact that they work is something everyone understands as soon as they flip a switch. What no one can see completely yet, though, is what happens on a small scale as a battery discharges.

Mostly encased in stainless steel, the inner workings of a battery have been difficult to measure directly. A much-heralded hire from two years ago, who divides her time between Stony Brook and Brookhaven National Laboratory, Esther Takeuchi has teamed up with several other scientists to gather new clues about the changes in a battery as it discharges.

“We’re looking at the internal anatomy of a battery without taking it apart,” said Takeuchi, a distinguished professor with an appointment in the department of chemistry and the department of materials Science and engineering at Stony Brook and a chief scientist at BNL’s Basic Energy Sciences Directorate.

Takeuchi and her team worked at BNL’s National Synchrotron Light Source, where they stopped batteries at various times and measured them with the kind of x-rays that penetrate the steel casing. These provide a resolution on the scale of 20 microns, which is about 1/4 the width of a human hair.

By understanding on a more precise level what happens inside a battery, scientists may provide insight that enables a greater understanding of the best architecture or design for a battery.

“The way we understand a battery could change dramatically,” said study co-author Amy Marschilok, a research associate professor in materials science and engineering at Stony Brook. “We’re taking” the inner workings of a battery “from black box science to more [open] science, where we can see and understand what’s happening. We’re on the verge of that type of discovery right now.”

In general, Takeuchi said batteries may work at about 80 percent efficiency, depending on the type of battery or its use. That, she said, could increase with a design that makes best use of the developing environment in the battery as it functions.

The results of the study, which included Takeuchi’s husband Kenneth, who is a distinguished teaching professor at Stony Brook, Marschilok, BNL scientist Zhong Zhong, BNL postdoc Kevin Kirshenbaum and Stony Brook graduate student David Bock, were published in the prestigious journal Science.

The research team used these bright x-ray beams to study lithium batteries that have a special silver material at the cathode, the place from which current departs, that has high stability, high voltage and spontaneous matrix formation.

As the batteries, which Bock created, discharge, lithium ions from the anode travel to the cathode, displacing silver ions in the process. Coupling with free electrons and unused cathode material, the displaced silver forms a conductive silver metal matrix that enables electrons to flow.

The research demonstrated that a slow discharge rate early in the battery’s life creates a more uniform network.

“When we started activating the battery, the cathode spontaneously, within its own structure, starts forming small parts, or ions, of silver metal,” Takeuchi said. “The silver ions are reduced to silver metal. What’s really interesting is that, because we’re forming silver metal, we have something we can measure.”

The results of the experiment provided a clearer understanding of the steps the battery goes through. The last part of the battery to activate is the center.

In some batteries, the flow of electrons may just reach the edges and never have access to the middle.

Takeuchi, who left the University at Buffalo to come to Long Island, said she is excited by the opportunities at Stony Brook and BNL. This past June, Stony Brook led a multi-institution group that received a $10 million Energy Frontier Research Center Award from the Department of Energy.

Takeuchi is convinced she made the right decision to move to Long Island.

“The willingness of Stony Brook and BNL to commit to this field was appealing to me,” Takeuchi said. “They recognize how important it is, to Long Island, nationally, and globally. We have the opportunity to make a difference.”

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Decreased sardine yield and rising water temperatures are part of global warming trend

As if the southern Caribbean weren’t already hot enough, the water temperature has climbed in the last 14 years at the same time that trade winds have weakened. While this may sound encouraging to scuba divers, it’s not such good news for plankton, the sardines that feed on them and the Venezuelan fishermen who depend on these small fish for their livelihood.

Above the Cariaco Basin, an ocean trench a few miles offshore from Venezuela, a local decline in trade winds has limited the movement of nutrient rich waters, contributing to a reduction in plankton production and, in part, to a collapse in local sardine fisheries, according to research by Gordon Taylor, a professor of microbiology at Stony Brook’s School of Marine and Atmospheric Sciences.

Working in collaboration with Mary Scranton, a Stony Brook professor, as well as researchers at several other U.S. and Venezuelan institutions, Taylor has traveled from Stony Brook to Venezuela every six months, monitoring oxygen, carbon, sulfur, nitrogen and other metals in the water, as well as the abundance and growth of microorganisms from the surface to the sea floor.

The decline in sardines, as measured by some of Taylor’s colleagues, has been dramatic. Sardine fishery landings were 40,000 tons in the last year, down dramatically from 200,000 tons in 2004. Overfishing also contributed to the steep drop.

Slower trade winds are a problem for the region because they interfere with a process called nutrient upwelling. The deeper, cooler regions of the ocean have more nutrients because that’s where plants and animals decompose. As this living matter sinks, it releases “the Miracle-Gro of the ocean,” Taylor explained.

The chemicals involved in water cycling through the ocean include nitrogen, phosphorous, silica and trace metals — some similar components people put on their lawns or potted plants.

The nutrients in the colder water typically cycle towards the surface. In upwelling, friction from winds pushes surface water away from the coast. That brings deeper, nutrient-rich water to the surface to replace it. With the change in the winds, the nutrients don’t reach the basin.

At the same time, the temperature of the water has increased by about 1.1 Celsius degree. While Taylor acknowledged that “1 degree doesn’t sound like a lot,” he urged people to “keep in mind that 1 degree represents a tremendous amount of heat being stored in the ocean.”

Global warming is causing both the higher water temperatures and the change in the trade winds, Gordon asserted.

“All indications from the International Panel on Climate Change is that the heat budget for the planet is on a one-way track at the moment because of fossil fuel combustion,” he said. “We continue to add more carbon dioxide to the atmosphere much faster than it’s being consumed.”

The Stony Brook professor said he has been aware of climate change for four decades, but his research has helped him understand the pace of that change.

“I was aware of the Greenhouse Effect back in my college days in the 1970s,” he indicated. “However, I remained skeptical about how fast it may be occurring, its dangers and didn’t appreciate the many ramifications of climate change until about 15 to 20 years ago.”

His studies, however, suggested “how fast the effects can be detected in the Tropics.” He cautioned that once the planet crosses a tipping point, the ecosystem can enter a “new state in a very short amount in time.”

Taylor lives in East Setauket with his wife, Janice, and their Rhodesian ridgeback dog, which is all of 113 pounds and is still not fully grown.

Their daughter Olivia just completed a program in fine arts. She lives in Manhattan, where she paints and sculpts, and works in a clothing boutique in SoHo.

Taylor has also studied the western part of the Long Island Sound, where he has examined the physical, chemical and biological causes of low oxygen levels, or hypoxia.
Taylor enjoys traveling to Venezuela, where he can continue to gather information, visit with colleagues, and study an area that he’s gotten to know well over the more than a decade since he started collecting water samples.

He has a “terrific set of friends” that he started this project with and, because he’s been doing this for so long, they’re all “growing old together.”

The microbes that are the subject of his work and his teaching at Stony Brook “are underappreciated,” he suggests. “We all owe our existence to them.”

Correction:
In the Power of Tree column that ran last week (Nov. 22), the caption for Esther Takeuchi incorrectly indicated her location. She was in her lab at Stony Brook University. She has a joint appointment from SBU and Brookhaven National Laboratory. The photo was provided by SBU. We regret the errors.